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4f-orbital covalency enables a single-crystal-to-single-crystal ring-opening isomerization in a CeIV–cyclopropenyl complex

https://doi.org/10.1038/s41557-025-01791-2

Vincenzini, Brett D; Yu, Xiaojuan; Paloc, Sébastien; Smith, Patrick W; Gupta, Himanshu; Pandey, Pragati; Kent, Greggory T; Ordonez, Osvaldo; Keller, Taylor; Gau, Michael R; et al (June 2025, Nature Chemistry)

Free, publicly-accessible full text available June 1, 2026
A Vanadium Methylidene

https://doi.org/10.1021/jacs.4c01906

Senthil, Shuruthi; Fehn, Dominik; Gau, Michael R; Bacon, Alexandra M; Carroll, Patrick J; Meyer, Karsten; Mindiola, Daniel J (June 2024, Journal of the American Chemical Society)

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